Semester

Spring

Date of Graduation

2001

Document Type

Thesis

Degree Type

MS

College

Eberly College of Arts and Sciences

Department

Physics and Astronomy

Committee Chair

Nancy C. Giles.

Abstract

In this thesis, I present a detailed study of Cd1-xZn xTe crystals with 0 ≤ x ≤ 0.14 using photoluminescence (PL) spectroscopy in the temperature range from 5 K to 300 K with the purpose of: (1) identifying various radiative transitions that are signatures of various point defects in bulk CdZnTe, (2) determining the zinc concentration in these crystals, and (3) identifying the nature of room-temperature PL. PL spectra at 5 K was used to determine the bandgap and hence the zinc concentrations. In the current state-of-the-art CZT grown for radiation detectors, it is common to observe 5-K PL spectra dominated by donor-bound exciton emission (D 0, X). Also, a deep acceptor-bound exciton (A0, X) related to a complex associated with Cd vacancies is usually detected. Thus, it was of interest to determine whether the "new" trend in bulk CZT growth would produce a different conclusion about the origin of the 300-K PL.

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