Semester

Summer

Date of Graduation

2006

Document Type

Dissertation

Degree Type

PhD

College

Eberly College of Arts and Sciences

Department

Chemistry

Committee Chair

Aaron T. Timperman.

Abstract

We have developed functional components for a comprehensive microfluidic system for proteomic analyses. This dissertation presents development of an electroomsotic pump for delivery of fluids to other microfluidic channels, a hydrodynamic flow restrictor for combining electrokinetic and hydrodynamic flow on a microfluidic chip-ESI-MS interface, and surface coatings to prevent analyte adsorption to microfluidic channels. A microfluidic chip ESI-MS interface with a novel voltage switching component is also developed for the separation of negative analytes at high pH, with positive ion mode ESI-MS detection of the analyte, converted to positive ions via a make-up solution induced pH change.

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