"Perturbation studies of excitable media" by Lisa Elizabeth Seagraves

Semester

Fall

Date of Graduation

1998

Document Type

Thesis

Degree Type

MS

College

Eberly College of Arts and Sciences

Department

Chemistry

Committee Chair

Kenneth Showalter

Committee Co-Chair

Paul Jagodzinski

Committee Member

Charles Jaffe

Abstract

Poly(N-isopropylacrylamide) (PNIPA) based systems are probably the most often studied polymer gels due to their dramatic change in volume, swelling and deswelling. Since this system has the best response to pH between 4 and 7, the ferrocyanide-iodate-sulfite (FIS) reaction, which exhibits pH oscillations between 4 and 7.5 in a continuously stirred tank reactor (CSTR), is a good candidate for studies of oscillatory gel systems.;This work also focused on two dynamical phenomena in the ruthenium catalyzed Belousov-Zhabotinsky (BZ) reaction. One is self-organized criticality and the other is periodic forcing and how they can be studied with the BZ reaction. Self-organized criticality is the ability of a system to organize itself into a critical state as a response to random perturbations. Periodic forcing gives rise to waves being sustained in a subexcitable medium by imposing periodic perturbations above and below the excitability limit.

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